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    EM 973

    Desenvolvimento eMeio Ambiente

    Arnaldo Walter

    UNICAMP

    [email protected]

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    Ciclos na natureza e o meio

    ambiente

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    Objetivos e contexto

    Ciclos da natureza so fundamentais para a manuteno da vida na

    Terra. O ciclo da gua um exemplo claro, e no preciso

    consideraes adicionais.

    Ciclos de nutrientes (como Nitrognio e Fsforo) so essenciais

    para as plantas e os animais.

    Alteraes nos ciclos da natureza no esto associadas ao

    deplecionamento dos reservatrios, mas sim alterao de

    fluxos entres os reservatrios (e consequente variao das

    condies fsico, qumicas e biolgicas), e poluio (alteraodas propriedades) dos sistemas da natureza (atmosfera, hidrosfera,

    biosfera e litosfera).

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    Princpios de Sustentabilidade (1)Miller and Spoolman. Living in the Environment : concepts, connections

    and solutions.

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    Princpios de Sustentabilidade (2)Miller and Spoolman. Living in the Environment : concepts, connections

    and solutions.

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    Natural cycles (1)http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2

    Natural cycles are the processes by which all essential materials

    flow through the living and the non-living parts of ecosystems.

    Ecosystems receive materials as inputs and release them as

    outputs. The cyclic path of material flow reuses the basic elements

    over and over. Natural cycles supply ecosystems with nutrients, energy and

    water.

    Examples are the water, the carbon and the nitrogen cycles.

    The smooth and steady functioning of cycles directly impactsecosystem stability. Conversely, disturbed cycles contribute

    directly to ecosystem vulnerability.

    http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2
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    Natural cycles (2)CSU -http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html

    Biogeochemical cycles are part of the larger cycles that describe

    the functioning of the whole Earth. Biogeochemical cycles

    correspond to the movement (or cycling) of matter through a

    system.

    The most important biogeochemical cycles affecting ecosystem

    health are the water, carbon, nitrogen, and phosphorus cycles.

    Biogeochemical cycles are cycles of materials or molecules

    through the atmosphere, the hydrosphere, the lithosphere and the

    biosphere.

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Biogeochemical

    cycles (CSU)

    Biologia + Geoqumica

    = Biogeoqumica

    Cincia que estuda o

    ciclo do carbono (por

    exemplo) e suasinterconexes com ciclos

    de outros elementos

    envolvidos no processo

    da vida (principalmente

    nitrognio, oxignio,

    fsforo e enxofre).

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    Nutrient cycles

    CSUColorado State University.

    http://www.colorado.edu/GeolSci/courses/

    GEOL1070/chap04/chapter4.html

    Movements through the

    atmosphere are generally rapid,

    while movements through the soils

    are generally slow.

    Increased transport by stream flow

    severely disrupts the cycles of

    elements without a gaseous phase.

    Movements from terrestrial

    biosphere to the ocean (via stream

    flow, usually) must be replaced by

    movements either through the

    atmosphere (such as with nitrogen

    and carbon) or by weathering (such

    as with phosphorous or calcium).

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Water cycle (1)CSU -http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html

    The most familiar of all

    cycles is the water

    cycle. The movement of

    water is critical in all

    cycles.

    The water cycle helps to

    demonstrate

    connections between

    local and globalecosystems.

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Water cycle (2)

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    Water cycle (3)flows in km3/yearhttp://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2

    Water vapor

    redistributes energy

    from the sun around

    the globe through

    atmosphericcirculation.

    Solar radiation drives

    evaporation. This

    process consumesnearly one-third of the

    incoming solar energy

    that reaches Earth's

    surface.

    http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2
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    Water cycle (4)CSU

    P: precipitation

    Total 496,000 km3/yr (land 111,000

    + ocean 385,000)

    E: evaporation

    Total 496,000 km3

    /yr (land 71,000+ ocean 425,000)

    T: transpiration included in plant

    evaporation

    R: surface runoff26,000 km3/yr

    SR: sub surface runoff(liquid12,000 + ice 2,000)

    I: infiltration 14,000 km3/yr

    S: springs 2,000 km3/yr

    1 km3/yr = one trillion liters/year

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    Water cycle (5)http://www.learner.org/courses/envsci/unit/text.php?unit=8&secNum=2

    Estimate of the world water balance. Source: MIT OpenCourseWare.

    Surface area

    (million km2)

    Volume

    (million km3)Volume (%)

    Equivalent depth

    (m)Residence time

    Oceans and seas 361 1,370 94 2,500 ~4,000 years

    Lakes andreservoirs

    1.55 0.13

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    Carbon cycle (1)

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    Carbon cycle (2)

    CSUColorado State University.http://www.colorado.edu/GeolSci/courses/GE

    OL1070/chap04/chapter4.html

    One of the most

    important to humans:

    one of the primaryelements forming

    human tissues;

    and because it is

    important to theclimate system;

    carbon dioxide (CO2)

    and methane (CH4) are

    GHG.

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Carbon cycle (3)CSU

    Fluxes to & from land: (GtC/year)

    P: photosynthesis -120

    PR: plant respiration - 60

    SR: soil respiration - 60

    SF: plants to soils - 60

    FFF: fossil fuel formation - 0.0001FFB: fossil fuel burning - 6

    DEF: deforestation - 2

    Fluxes to & from ocean: (GtC/year)

    D: dissolving - 107

    E: exolving - 103CP: carbonate formation - 4

    W: weathering - 0.6

    Fluxes from volcanoes: (GtC/year)

    V: 0.1

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    Carbon cycle (4)IPCC (2003)

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    Carbon cycles (5): carbon residence timeCSU

    Some in fluxes are not balanced by out fluxes (e.g., the

    atmosphere and fossil fuels). So residence time are slightly

    different (and reservoirs are growing... or shrinking).

    The RT of carbon in the air (mostly CO, but some CH4) is long

    enough that the air is well mixed (mixes in about 1 year).

    The RT of soils: some parts cycle very slowly (1,000's of years),

    some parts very rapidly (a few weeks to monthse.g., leaves)

    The RT of fossil fuels reflects all fuels suspected to exist: coal:

    ~ 350 years; oil: ~ 40 years; natural gas: ~ 60 years.

    The RT of ocean: the surface water (short RT, few months to

    years) and deep water (long RT, 200 to 400 years). Ocean RT

    reflects the circulation of the ocean (deep water formation).

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Carbon cycles (6): silicatesCSU

    Long term cycle of the carbon cycle, tied with the rock (silicate) cycle. The time

    scale for this cycle is millions to hundreds of millions of years.

    On this time scale, carbon cycling by plants, oceans and the atmosphere is

    thought to be in balance (steady state orequilibrium) ... so carbon dioxide levels

    in the atmosphere are thought to be controlled by weathering rates and rates of

    volcanic eruptions.

    Weathering rates are thought to be controlled by rate of tectonic uplift: more

    uplift, more weathering and less atmospheric carbon dioxide. This may explain

    the slow decline in atmospheric carbon dioxide from levels of several thousand

    ppm about 100 million years ago, to 280 ppm in the pre-industrial time: during

    this time, the Tibetan Plateau and Rocky Mountain Plateau were raised by

    tectonic activity.

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Nitrogen cycle (2)

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    Nitrogen cycle (3): chemical cycles and

    reservoirs (CSU)

    F = fixation;

    D = denitrification ;

    O = oxidation .

    Atmosphere: 4,000,000 Gt

    Land Plants: 3.5

    Soils: 9.5 Gt

    Oceans: 23,000 Gt

    Sediments and rocks:

    200,000,000 Gt

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    Nitrogen cycle (4):

    fluxes (CSU)

    Fluxes: (in Mtyear )

    LF: Land Fixation 140

    LD: Land denitrification 130

    OF: Oceanic Fixation 50

    OD: Oceanic denitrification 110

    I: Industrial dixation 100FFB: Fossil fuel burning 20

    BB: biomass burning 10

    L: Lightning 20

    D: Decay 1200

    G: Growth 1200L-O: Land-to-Ocean 48 (rivers

    36; dust 6; NOx 6)

    O-L: Ocean-to-Land 15 (sea

    spray)

    Burial: 10

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    Nitrogen cycles (5)CSU

    Industrial fixation is used to make fertilizers to provide usable

    nitrogen for crops. This flux is comparable to natural fixation.

    Specialized bacteria and lightning are the only natural ways that

    nitrogen is fixed.

    How did agriculture survive before fertilizers? Early civilizations

    had to rely on natural regeneration of fixed nitrogen:

    Annual floods bring fresh sediments (e.g., Nile Valley);

    Slash/burn agriculture: once the soil nutrients are depleted,

    move on to a new place;Crop rotation: certain crops (e.g. soybeans) are good at fixing

    nitrogen, others (e.g. corn) use it up; plant on alternate years.

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Nitrogen cycles (6): residence timesCSU

    Nitrogen in the atmosphere: 14 million years; land plants: ~ 3 years; oceans: ~

    20,000 years; soils: ~ 9 years

    As pollutants: NOx ~ 4 days and as N2O ~ 120 years.

    In reservoirs where N2 is the dominant form (of nitrogen) (e.g., atmosphere,

    ocean), the residence times is long.

    In reservoirs where fixed nitrogen is dominant (e.g., soils, plants), the residence

    times is short.

    N2 is very stable, but fixed nitrogen compounds are very reactive (that's why

    plants can utilize them).

    Eutrophication corresponds to increasing the nutrients in a body of water.Runoff carrying excess nitrate fertilizers enriches these bodies of water;

    algae respond to this first and excess algae implies depletion of O2 in the water.

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Phosphorus cycle (1)

    Importance: phosphorus is a necessary, limiting nutient and

    Phosphate runoff causes eutrophication.

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    Phosphorus cycle (2)

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    Phophorus cycle (3): reservoirsCSU

    Earth's Crust: 20,000,000,000 Mt

    ( recoverable : ~20,000) (most of

    the phosphorus is in rocks).

    Ocean: 100,000 Mt; Freshwater:

    ~100 Mt; Land Plants: ~3,000 Mt;

    Soils: ~100,000 Mt.

    Main fluxes (Mt/year)

    M: Mining - 50 (humans)

    F: Fertilization - 50 (humans)

    W: Weathering -10

    R: Runoff - 20

    B: Burial - 13

    D: Decay - 200

    G: Growth - 200

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    Phosphorus cycles (5): fluxesCSU

    Ocean deposits: 5,000 years (with respect to input). Availability to

    marine organisms is limited by the fact that most P is in the deep

    ocean.

    Land deposits: for phosphate rocks, 44 years.

    Longer if less concentrated deposits are mined (~ 175 years).

    http://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.htmlhttp://www.colorado.edu/GeolSci/courses/GEOL1070/chap04/chapter4.html
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    Ciclos na natureza (2)(Klee e Graedel, 2004))

    A mobilizao antropognica deCarbono, Nitrognio e Fsforo.

    O problema est em que tais

    mobilizaes alteram ciclos vitais

    no planeta.

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    MobilizaoAntropognica [Gg/ano]

    MobilizaoNatural [Gg/ano]

    Minerao ________ Decaimentono oceano

    4.860 Mobilizao

    total

    [Gg/ano]

    118.450.281

    Fsseis 7.013.630 Oceano p/atmosfera

    9.991 Antropognica/Natural

    10,37%

    Biomassa 4.110.800 Produode plantas

    107.311.000 Antropognica/Total

    9,39%

    Total 11.124.430 Total 107.325.851

    Ciclo de CarbonoKlee e Graedel (2004)

    Gg = 1.000 t