cantabria campus internacional, programa de formaciÓn transversal escuela de doctorado de la uc...

CANTABRIA CAMPUS INTERNACIONAL

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PROGRAMA DE FORMACIÓN TRANSVERSAL

Escuela de Doctorado de la UC (EDUC)

•Proyectos coordinados

Inmaculada Ortiz UribeDepartamento de Ingeniería Química y BiomolecularUniversidad de Cantabria. E.mail: [email protected]


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* Gestora de los Planes Nacionales de I+D en

Medio Ambiente

Procesos y Productos Químicos, 1998-2002

* Coordinadora del área ANEP Tecnologías Químicas y Medio Ambiente, 2005-08

*Representante española en el Comité Científico INTAS, 2003-06

*Representante española en el Dominio ESSEM, Programa COST, 2013-17


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• ¿Qué es un proyecto coordinado?


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Escuela de Doctorado de la UC (EDUC)• BOLETÍN OFICIAL DEL ESTADO Núm. 266 Miércoles 6 de noviembre

de 2013 Sec. III. Pág. 89319

• Los proyectos coordinados deberán reunir las siguientes características:

• a) Estarán formados por un mínimo de dos y un máximo de seis subproyectos. Uno de los subproyectos será liderado por el investigador principal coordinador de la investigación, que será responsable de su seguimiento y de su coordinación científica. Si el subproyecto tiene dos investigadores principales, ambos serán considerados coordinadores.

• b) Los subproyectos podrán ser de tipo A o B, si bien el subproyecto del coordinador deberá ser de tipo B, y podrán ser de distintas entidades beneficiarias o de la misma, siempre que, cuando sean de la misma entidad, se aporte una dimensión de relevancia para el proyecto coordinado que no pueda ejecutarse con un proyecto individual con dos investigadores principales.


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• 2 Casos de estudio

• Programa Consolider-Ingenio, 2006-2010

• 7º Programa Marco de la UE, Programa de colaboración con SME


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Escuela de Doctorado de la UC (EDUC)• Ingenio 2010• 2010 como plazo para acercar al 3% del PIB la inversión europea

en Investigación y Desarrollo.• Programa INGENIO 2010, un compromiso que pretende involucrar

al Estado, la Empresa, la Universidad y otros Organismos Públicos de Investigación

• Los Proyectos CONSOLIDER• Definición: los Proyectos CONSOLIDER ofrecen financiación de

larga duración (5-6 años) y de gran tamaño (1-2 millones de euros) para grupos y redes de investigación excelentes en cualquiera de las áreas de conocimiento del Programa Nacional de I+D+i.

• Objetivos: los objetivos de esta iniciativa son aumentar el tamaño medio de los grupos de investigación, incrementar la dotación financiera de las mejores líneas de investigación, romper con el excesivo fraccionamiento de las investigaciones e impulsar la participación de los centros públicos de investigación en el Programa Marco europeo.


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• El objetivo fundamental es aprovechar la experiencia de 23 grupos de investigación en diferentes áreas para abordar de una manera integral la reutilización de aguas residuales urbanas depuradas.

PROGRAMA TRAGUA"Tratamiento y reutilización de aguas

residuales para una gestión sostenible"

CONSOLIDER -INGENIO 2010. Ministerio de Educación y Ciencia


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Source: European Environment Agency http://www.eea.europa.eu/themes/water/featured-articles/water-scarcity

EUROPEAN WATER SCARCITY


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Source: Fundación Cajamar (MARM) Informes y monografías 22: “La desalación en España”

Evolution and tendency of the water reservoir in Spain (1995-96 to 2007-08) in Hm3


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Países Desarrollados Países Pobres

Usos del agua en el mundoRío

Regadío

Uso Agrario


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INDUSTRIAL USE WWTP

DISCHARGE

Treated water

Reclaimed

waterCOLLECTING AND PURIFICATION OF

WATER

REUSE

URBAN USE

AGRICULTURE USE

RECREATIONAL USE

TERTIARY TREATMENT


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• Reuse of reclaimed water in SPAIN (2006) = 368 Hm3 yr-1

Agricultural Irrigation

Recreation

Environmental Purposes

Municipal Uses

72%17%

7% 4%

(Source: Water Reuse Markets, 2005; CEDEX, 2006)

http://images.google.es/imgres?imgurl=http://www.coffsharbour.nsw.gov.au/resources/images/Web_Golf_Course_2.jpg&imgrefurl=http://www.coffsharbour.nsw.gov.au/www/default.asp?guiValue%3DB186C84D-4B39-4EAF-A797-4643DA9664F4&h=166&w=285&sz=15&hl=es&start=15&um=1&tbnid=q9FttT0bqwFRfM:&tbnh=67&tbnw=115&prev=/images?q%3Dreclaimed%2Bwater%2Bgolf%26um%3D1%26hl%3Des%26rlz%3D1T4GGIK_esES219ES219


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ESQUEMA DEL MODELO DE GESTIÓN Y COORDINACIÓN DE TRAGUA


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Escuela de Doctorado de la UC (EDUC)Desarrollo sostenible: “Desarrollo que garantiza las necesidades del presente sin comprometer las posibilidades de las generaciones futuras para satisfacer sus propias necesidades ” Informe Bruntland, 1987

-Producción y Consumo sostenible.-Uso eficiente de energías renovables.-Gestión adecuada de los productos químicos.-Integración de los costes ambientales en las políticas de desarrollo

Desarrollo económico

Responsabilidad social

Protección Ambiental

Cumbre Mundial sobre Desarrollo Sostenible, 2002 Johannesburgo


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http://www.canstockphoto.es/verde-faacute;brica-6456552.html

http://www.canstockphoto.es/verde-faacute;brica-6456552.html

http://dibujos.name/wp-content/uploads/2010/11/vaca.jpg


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OZONIZACIÓN

POAs con ozono

O3

O3/H2O2

O3/UVO3/H2O2/UV


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2.

ANODE: BORON-DOPED DIAMONDFormation potential of typical chemical reactants

Potential of oxygen evolution of differents anodes, V vs. NHE

2.

Electrooxidation


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Bacterias, virus, parásitos

Reutilización urbana y de recreo

Tratamiento primario

Tratamientos requeridos para los principales usos de agua reutilizada

Descarga directa

Riego

Reutilización industrial

Reutilización para agua

potable

Recarga de acuíferos

Contaminación orgánica

Nutrientes (N, P)

Sólidos en suspensión

Microcontaminantes orgánicos

Sales

Metales pesadosSales disueltas

Metales, sales

Bac

teria

s,vi

rus,

pará

sitos

(desinfección)

Con

t. or

gáni

ca

Nut

rient

es (

N, P

)S

ólid

ossu

spen

sión

en

Microcont. orgánicos

MC

O

Met

ales

, sa

les

Sales

Metales Salespesados

disueltas


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7º Programa Marco de la UE, Programa de colaboración

con SME


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Figure 1.1.: Hourly rates European values compared to low wages countries


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Research for the benefit of the SME, T7th Framework Programme

The aim is to strengthen the 'innovation capacity' of small and medium-sized enterprises (SMEs) in Europe and their contribution to the development of new technology based products and markets. The programme will help them outsource research, increase their research efforts, extend their networks, better exploit research results and acquire technological know how, bridging the gap between research and innovation


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PARTNERS: • 3 AG: Associated Groups • 6 SME: Small and Medium Enterprises• 5 RTD: Research and Technological Development Institutions• 1 OTHER

PROJECT STRUCTURE

LENGTH: 36 months

7th Framework Programme (7FP) of the European Commission

TITLE: Towards an Innovative Galvanic Industry (TIGI)

COUNTRIES: • NL: The

Netherlands• S: Sweden• ES: Spain

European Commission

RTD’s

AG’s

SME’s


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Spain

Sw

eden

The Netherlands


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Pre-treatment steps: chemical degreasing,

rinse, pickling, etc.

Automotive components

Electroplated Components

Passivated components

Zinc Electroplating

1st Surface Treatment Step

Chromium Passivation2nd Surface Treatment Step


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Health and environmental risk

The End of Life Vehicle (European Directive 2000/53/CE)

Waste electrical and electronic equipment (European Directive

2002/96/CE).

Cr6+

Cr3+

PASSIVATIONPASSIVATION


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Figure 1.2.: Passivating bath stabilized by EPT


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Escuela de Doctorado de la UC (EDUC)OVERALL OBJECTIVE:

The overall purpose of the project is to greatly enhance the competitive power of the European galvanic industry by implementing emulsion pertraction technology for this sector. The following strategic objectives are: i) extend the lifetime of new passivating baths with at least a factor 10, ii) reduce the waste quantities, produced from spent passivating baths, by 90 % and iiii) improve the quality of the passivating operation by 90%.

:

Objectives

Workpackages

Tasks Deliverables

1. Baseline

2A. R&D

2B. Modeling

4 Long-term pilot tests

5. Evaluation 6.Training/ Dissemination/ Exploitation

3. Design / Manufacture / Install

7. Management

Time


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PROCESS CONCEPTUAL DESIGN

Zinc Electroplating

Basic pH

Passivation

Final fitting-out

Regeneration of spent

passivation baths by EPT

H2SO4

Electrolytic recovery of

Zinc

ZnSO4

Recovery of metallic

Zinc

Surface treatment processSpent passivation bath

Regenerated passivation bath

Residual Stream: ZnSO4 in acid

media

Pre-treatment


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Beneficiary Number *

Beneficiary name Beneficiary short name

Country Date enter project**

Date exit project**

1 AG Vereniging van ondernemingen in de galvanische industrie

NGO Nl Month 1 Month 36

2 AG Svensk Ytbehandling Forning

SYF S Month 1 Month 36

3 AG Asocation de Industrias de Acabados de Superfucies

AIAS Es Month 1 Month 36

4 SME end-user Galvano Techniek Veenendaal

GTV Nl Month 1 Month 36

5 SME end-user Loko Gramsbergen Loko Nl Month 1 Month 366 SME end-user Vårgårda Kromverk AB Vargarda S Month 1 Month 367 SME end-user Ytab Aviken AB Ytab S Month 1 Month 368 SME end-user Zinper SL Zinper Es Month 1 Month 369 RTD The Organisation for

Applied Scientific Research

TNO Nl Month 1 Month 36

10 RTD Gemini Enterprises GE Nl Month 1 Month 3611 RTD Ondeo Industrial Solutions Ondeo Nl Month 1 Month 3612 RTD Universidad de Cantabria UC Es Month 1 Month 3613 RTD Swerea IVF IVF S Month 1 Month 3614 Other Proton Proton S Month 1 Month 3615 SME end-user Galvanotecnia y Derivatos Galvanotecnica Es Month 1 Month 36

LIST OF BENEFICIARIES


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Escuela de Doctorado de la UC (EDUC)ID Task Name

1 Kick Off

2 WP 1: Baseline situation

3 D 1.1: Report on baseline situation & w orking document

4 M 1.1

5 WP 2: R&D

6 D 2.1: Report on batch w ise emulsion

7 M 2.1

8 D 2.2: Report on accumulation of pollutants

9 M 2.2

10 D 2.3: Report on model dev. & EPT model process

11 M2.3

12 WP 3: Pilot installations

13 D 3.1: Basic engineering plan

14 D 3.2: Detailed engineering plan

15 M 3.1

16 D 3.3: Emulsion pertraction test unit built

17 M3.2

18 WP 4: On-site EPT pilot test

19 D 4.1 Report on tests and optimalisation of EP units

20 M 4.1

21 WP 5: Evaluation

22 D 5.1: Technical, economical & environmental evaluation report

23 M 5.1

24 WP 6: Training, Dissemination, Exploitation

25 D 6.1: TIGI w ebsite on-line

26 D 6.2: Training Sessions for Ags & SMEs

27 M 6.1

28 D 6.3: Exploitation plan

29 M6.2

30 WP 7: Management

31 D 7.1: Project Agreement

32 D 7.2.1: Midterm plan for using/disseminating

33 M7.1

34 D 7.2.2: Final plan for using/disseminating

35 M7.2

-2 -1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41J A S O N D J F M A M J J A S O N D J F M A M J J A S O N D J F M A M J J A S O N D J

Half 2, 2008 Half 1, 2009 Half 2, 2009 Half 1, 2010 Half 2, 2010 Half 1, 2011 Half 2, 2011 Half 1, 2012

Figure 1.4.2.: Gannt chart of the project


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Work package

No

Work package title

Type of activity

Lead participant

No

Lead participant Short Name

Person-months

StartMonth

End month

1 Baseline situation

RTD 1 NGO 23,5 1 12

2 Research and Development

RTD 9 TNO 85,2 1 32

3 Design, manufacture and set-up of pilot inallations

RTD 11 ONDEO 34,3 6 24

4 On-site EPT pilot tes at the partner SMEs

RTD 10 GE 55,9 15 33

5 Evaluation RTD 9 TNO 23,2 1 366 Training,

Dissemination & Exploitation

RTD 1 NGO 20,4 16 36

7 Management MGT 10 NGO 22,4 1 36TOTAL 264,9

WORK PACKAGE LIST


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Escuela de Doctorado de la UC (EDUC) WORK PACKAGE LISTNo,

Deliverable Title WPNo.

Lead bene-ficiary

Eimated indicative person- months

Nature Dissemination

level

Deliverydate

1.1 Report on baseline situation.and working document

1 GE 23.5 R RE 12

2.1 Report on batch wise emulsion pertraction tes with passivating bath liquids, incl. regeneration options.

2 TNO 28.5 R RE 30

2.2 Report on accumulation of pollutants in passivating bath liquids, methods for their removal, and their effects on product qualities.

2 IVF 42.7 R RE 30

2.3 Report on model development and EPT model process calculations.

2 UC 14 R CO 32

3.1 Basic engineering plan. 3 GE 18.3 R CO 143.2 Detailed engineering plan. 3 ONDEO 5 R CO 173.3 Emulsion pertraction pilot te units built for all 7

partner SMEs. 3 ONDEO 11 7 P CO 18-24

4.1 Report on tes and optimisation of emulsion pertraction units on site of SMEs.

4 GE 55.9 R RE 33

5.1 Report on technical, economic and environmental (incl. LCA analysis) evaluation.

5 TNO 23.2 R RE 36

6.1 TIGI project website on-line 6 GE 1 O PU/CO 26.2 Training sessions for AGs and SMEs. 6 ONDEO 12.4 O RE 18-266.3 Exploitation plan. 6 NGO 7 R CO 367.1 Consortium Agreement 7 NGO 4 R CO 27.2.1 Midterm plan for using and disseminating the

knowledge. 7 NGO 9.1 R CO 18

7.2.2 Final plan for using and disseminating the knowledge.

7 NGO 9.3 R CO 36

TOTAL 264.9


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Escuela de Doctorado de la UC (EDUC) LIST OF MILESTONEMilestoneNumber

Milestone Name

WPs no’s.

Lead beneficiary

Delivery date from Annex I

Comments(Means of verification)

M1.1 Baseline situation defined 1 GE 12 Deliverable 1.1. Approved by PSC

M2.1 Batch wise EP test completed, and Effects of pollutants on product quality assessed.

2 TNO 30 Deliverable 2.1. & 2.2 results evaluated (ISO 9001)

M2.2 EPT mathematical model validated

2 UC 32 Deliverable 2.3. Model approved by PSC

M3.1 EP units ready for shipment to SMEs

3 Ondeo 18-24 Deliverable 3.3.7 Pilot passes factory test.

M4.1 On site EPT pilot tes completed 4 GE 33 Deliverable 4.1. Results approved by PSC.

M5.1 Technical, environmental and economical evaluation ready

5 TNO 36 Deliverable 5.1. Approved by PSC

M7.1 Completed knowledge dissemination and exploitation reports

7 NGO 18 & 36 Deliverables 6.3, 7.2.1 & 7.2.2. Validated by PSC


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Escuela de Doctorado de la UC (EDUC)Project objectives related to indicators expected date and project resultsObjectives Indicator Date Linked project

resultExtend lifetime new developed passivating bath with factor 10

Demonstration of EPT unit at metal platers showing this result, and M4.1

Month 33-36 D 4.1, D5.1

Reduce waste with 90% Demonstration of EPT unit at metal platers showing this result and M5.1

Month 33-36 D4.1, D5.1

Reduce off-spec product by 90%

Demonstration of EPT unit at metal platers showing this result and M5.1

Month 33 D4.1, D5.1

Develop modelling theory for mass transfer test

150 mg/h FE and 4 gr/h Zn removal and M2.1

Month 32 D2.3

Determine selectivity of extraction liquids

Selectivity for Fe3+ and Zn 2+ factor 100 higher then for Cr3+ M2.1, M4.1 and M5.1

Month 36 D2.1

Top 3 parameters for product quality

Multi criteria analyses of parameters influencing product quality M2.1

Month 30 D2.2

Target price EPT unit 45.000 to 60.000 euro

Price calculations of average unit and M3.1

Month 24 D3.3

Pay back time of EPT unit <1 year.

Cost effectiveness calculation at metal platers and M 5.1

Month 36 D4.1, D5.1


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Contingency planning:

1. One of the RTD partners cannot fullfill its task: Since most of the RTD partners (TNO, Ondeo, GE and UC) have work with the principle of the EP technology before the unfulfilled task will be divided over the other RTD partners.

2. One of the SME´s cannot fullfill its tasks: The AG´s of the various countries are responsible for the partitipation of their SME´s. In such a case the AG of the country concerned will enroll a replacement SME to the consortium.

3. One of the AG´s cannot fulfill its tasks: If their tasks cannot be ported to the other AG´s, the German AG will take place of the AG concerned.


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AAC

C

CAAC

Back-extraction

Emulsion

A

ACCA AC

Pore

FeedSolution

Emulsion

Hollow fiber

C

Strippingdroplet

Extraction

Hollow Fiber ContactorFeed Solution

Masstransfer

Emulsion Tank

Rafinate

Concentrate


,



•Proyectos coordinados

Inmaculada Ortiz UribeDepartamento de Ingeniería Química y BiomolecularUniversidad de Cantabria. E.mail: [email protected]


,


Escuela de Doctorado de la UC (EDUC)Desarrollo sostenible: “Desarrollo que garantiza las necesidades del presente sin comprometer las posibilidades de las generaciones futuras para satisfacer sus propias necesidades ” Informe Bruntland, 1987

-Producción y Consumo sostenible.-Uso eficiente de energías renovables.-Gestión adecuada de los productos químicos.-Integración de los costes ambientales en las políticas de desarrollo

Desarrollo económico

Responsabilidad social

Protección Ambiental

Cumbre Mundial sobre Desarrollo Sostenible, 2002 Johannesburgo


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Motivation

Spent Passivation Bath

Treated bath (Cr3+, pH=acid)

Zn concentrated solution

[Cr3+]≈constant [Zn2+]< MAV

[Fe3+ ]< MAVFe3+

Zn2+

EMULSION PERTRACTION PROCESS

Recovery of Zn2+

Removal of Zn2+ and Fe3+

Fe3+

Zn2+

Dissolution of steel components

Dissolution of zinc coatings

[Fe] < MAV

[Zn] < MAV

SPENT PASSIVATION BATH

[Fe] > MAV

[Zn] > MAVMAV: Maximum acceptable value

REGENERATION OF SPENT PASSIVATION

BATHS


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Proof of concept

Feed solutionProperty Value

pH ≈2

Component

Concentration (mg/L)

Cr+3 4500-7500

Zn+2 2500-11780

Fe+3 20-40

Spent passivationbath

Emulsion

Hollow Fiber Contactor

Stripping solution

Organic solution

pH control

Emulsion composition Organic solution (80%

v/v):

Cyanex®272/ShellsolD70

Stripping solution (20% v/v):

Strong acid (HCl, H2SO4)

Extraction Isothermes Cyanex 272

0

20

40

60

80

100

0 2 4 6 8pH

% E

xtra

ctio

n

Cr3+

Zn2+

Fe3+

pH 2

-3

Extraction isothermes Cyanex 272


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WASTEWATER CONTAINING METALLIC POLLUTANTS

HIGH TOXICITY COMPOUNDS

ENVIRONMENTAL PROBLEM

1. M

OT

IVA

TIO

N

Reduction at the origin

Recycling, Recovery, Reuse

Treatment

Disposal

Clean Productio

n

Minimizing Effluent

Generation

EUROPEAN POLICY OF WASTE MANAGEMENT

BEST AVAILABLE TECHNIQUES (BAT)

Protection of natural resources

Legal standards

Selective recovery of valuable

compounds for reuse

Treatment Recovery

(IPPC DIRECTIVE 96/61/EC)

BEST AVAILABLE TECHNIQUES (BAT)

CLEAN TECHNOLOGIES

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