repositorio-aberto.up.pt · repositorio-aberto.up.pt ... 16 ... 17
TRANSCRIPT
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αβαβ
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)()()(10.)(2.)(6.)(10 26434
2 sOHPOCaaqOHaqPOaqCa ↔++ −−+
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( ) ( ) )()()(6)()()10( 26410
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22 sOHPOZnCaaqOHaqPOaqZnxaqCax xx−−−++ →+++−
( ) ( ) ( ) ( ) )()()()( 226410
226410 aqCaxsOHPOZnCaaqZnxsOHPOCa xx
OH+
−+ +→+
−
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Lopes,J.C.B. et al., (2005) “Network Mixer and Related Mixing Process”, PCT/IB2005/000647, Patente Europeia EP172643 B1, 2008.
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0363 g Sample Volume: 0.007941 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 64.4 min End of run: 2009/07/02 13:58:34 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/02Analysis performed by:............................................................................................................................................................................................................................................................................................................AlexandreComments:............................................................................................................................................................................................................................................................................................................Rod 66Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: AInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.0363 gVolume:............................................................................................................................................................................................................................................................................................................0.007941 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.0 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0363 g Sample Volume: 0.007941 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 64.4 min End of run: 2009/07/02 13:58:34 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0363 g Sample Volume: 0.007941 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 64.4 min End of run: 2009/07/02 13:58:34 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 1 of 5
Ads Des
0.00
4.00
8.00
12.00
16.00
20.00
24.00
28.00
32.00
36.0039.10
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0363 g Sample Volume: 0.007941 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 64.4 min End of run: 2009/07/02 13:58:34 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 2 of 5
Slope = 30.715Intercept = 3.645e-01
Correlation coefficient, r = 0.999984C constant= 85.268
Surface Area = 112.052 m!/g
MBET summary
A D BF
0.0000
2.0000
4.0000
6.0000
8.0000
10.0000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
8.29870e-02 24.7434 2.9263e+00 2.24497e-01 31.9736 7.2441e+001.52281e-01 28.5714 5.0305e+00 2.96334e-01 35.5415 9.4805e+00
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 3 of 5
Thickness method: DeBoerSlope = 7.726
Intercept = -2.997Correlation coefficient, r = 1.000000
Micropore volume = 0.000 cc/g
Micropore area = 0.000 m!/gExternal surface area = 112.052 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 3 of 5
A D BF
-3.30.0
4.0
8.0
12.0
16.0
20.0
24.0
28.0
32.0
36.039.1
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+005.490e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample A_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{518555213:20090702 144944375} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0133 g Sample Volume: 0.006979 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 68.2 min End of run: 2009/07/02 14:02:23 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/02Analysis performed by:............................................................................................................................................................................................................................................................................................................AlexandreComments:............................................................................................................................................................................................................................................................................................................rod 67Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: BInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.0133 gVolume:............................................................................................................................................................................................................................................................................................................0.006979 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.5 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0133 g Sample Volume: 0.006979 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 68.2 min End of run: 2009/07/02 14:02:23 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0133 g Sample Volume: 0.006979 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 68.2 min End of run: 2009/07/02 14:02:23 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 1 of 5
Ads Des
0.00
8.0012.0016.0020.0024.0028.0032.0036.0040.0044.0048.0052.0056.0060.0064.00
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0133 g Sample Volume: 0.006979 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 68.2 min End of run: 2009/07/02 14:02:23 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 2 of 5
Slope = 18.017Intercept = 1.567e-01
Correlation coefficient, r = 0.999997C constant= 115.958
Surface Area = 191.626 m!/g
MBET summary
A D BF
0.00000.4000
0.8000
1.2000
1.6000
2.0000
2.4000
2.8000
3.2000
3.6000
4.0000
4.4000
4.8000
5.2000
5.6000
6.0000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
8.59710e-02 44.1399 1.7049e+00 2.27074e-01 55.2652 4.2533e+001.56099e-01 49.8746 2.9674e+00 2.98380e-01 61.5365 5.5295e+00
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 3 of 5
Thickness method: DeBoerSlope = 13.675
Intercept = -6.860Correlation coefficient, r = 1.000000
Micropore volume = 0.000 cc/g
Micropore area = 0.000 m!/gExternal surface area = 191.626 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 3 of 5
A D BF
-7.5
0.04.08.0
12.016.020.024.028.032.036.040.044.048.052.056.060.064.0
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+00 5.510e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample B_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{588686653:20090702 145041140} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0501 g Sample Volume: 0.019945 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 67.5 min End of run: 2009/07/03 12:37:59 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/03Analysis performed by:............................................................................................................................................................................................................................................................................................................AlexandreComments:............................................................................................................................................................................................................................................................................................................Rod 66Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: AInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.0501 gVolume:............................................................................................................................................................................................................................................................................................................0.019945 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.0 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0501 g Sample Volume: 0.019945 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 67.5 min End of run: 2009/07/03 12:37:59 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0501 g Sample Volume: 0.019945 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 67.5 min End of run: 2009/07/03 12:37:59 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 1 of 5
Ads Des
0.00
4.00
8.00
11.10
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qpsSample Desc: Pó Comment: Rod 66Sample weight: 0.0501 g Sample Volume: 0.019945 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 67.5 min End of run: 2009/07/03 12:37:59 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 2 of 5
Slope = 110.158Intercept = 1.116e+00
Correlation coefficient, r = 0.999840C constant= 99.737
Surface Area = 31.297 m!/g
MBET summary
A D BF
0.0000
4.0000
8.0000
12.0000
16.0000
20.0000
24.0000
28.0000
32.0000
36.0000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
8.72020e-02 7.0446 1.0850e+01 2.28418e-01 9.0884 2.6062e+011.57107e-01 8.1315 1.8340e+01 3.01095e-01 10.0048 3.4453e+01
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 3 of 5
Thickness method: DeBoerSlope = 1.959
Intercept = 0.170Correlation coefficient, r = 1.000000
Micropore volume = 0.000 cc/g
Micropore area = 0.988 m!/gExternal surface area = 30.309 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 3 of 5
A D BF
0.0
4.0
8.0
11.1
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+00 5.530e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample C_II_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1173960324:20090703 134524921} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.1271 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.9 min End of run: 2009/07/02 18:23:54 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/02Analysis performed by:............................................................................................................................................................................................................................................................................................................MBRComments:............................................................................................................................................................................................................................................................................................................Rod 5Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: AInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.1271 gVolume:............................................................................................................................................................................................................................................................................................................0 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.0 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.1271 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.9 min End of run: 2009/07/02 18:23:54 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.1271 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.9 min End of run: 2009/07/02 18:23:54 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 1 of 5
Ads Des
0.00
8.0012.0016.0020.0024.0028.0032.0036.0040.0044.0048.0052.0056.00
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.1271 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.9 min End of run: 2009/07/02 18:23:54 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 2 of 5
Slope = 20.303Intercept = 1.566e-01
Correlation coefficient, r = 0.999986C constant= 130.658
Surface Area = 170.218 m!/g
MBET summary
A D BF
0.0000
0.8000
1.2000
1.6000
2.0000
2.4000
2.8000
3.2000
3.6000
4.0000
4.4000
4.8000
5.2000
5.6000
6.0000
6.4000
6.8000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
7.83490e-02 38.8344 1.7515e+00 2.28949e-01 49.5961 4.7903e+001.56161e-01 44.4945 3.3278e+00 3.00282e-01 54.8271 6.2627e+00
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 3 of 5
Thickness method: DeBoerSlope = 11.397
Intercept = -2.319Correlation coefficient, r = 1.000000
Micropore volume = 0.000 cc/g
Micropore area = 0.000 m!/gExternal surface area = 170.218 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 3 of 5
A D BF
-2.6
4.0
8.0
12.0
16.0
20.0
24.0
28.0
32.0
36.0
40.0
44.0
48.0
52.0
56.0
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+00 5.520e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/02 Operator: Date:7/2/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample D_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{544298624:20090702 184808687} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0547 g Sample Volume: 0.016611 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 72.9 min End of run: 2009/07/03 12:43:25 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/03Analysis performed by:............................................................................................................................................................................................................................................................................................................AlexandreComments:............................................................................................................................................................................................................................................................................................................rod 67Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: BInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.0547 gVolume:............................................................................................................................................................................................................................................................................................................0.016611 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.5 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0547 g Sample Volume: 0.016611 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 72.9 min End of run: 2009/07/03 12:43:25 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0547 g Sample Volume: 0.016611 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 72.9 min End of run: 2009/07/03 12:43:25 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 1 of 5
Ads Des
0.00
4.00
8.00
12.00
16.00
20.00
24.00
28.00
32.00
36.00
40.00
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qpsSample Desc: Pó Comment: rod 67Sample weight: 0.0547 g Sample Volume: 0.016611 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 72.9 min End of run: 2009/07/03 12:43:25 Instrument: Nova Station BCell ID: 67
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 2 of 5
Slope = 30.146Intercept = 2.243e-01
Correlation coefficient, r = 0.999830C constant= 135.429
Surface Area = 114.670 m!/g
MBET summary
A D BF
0.0000
2.0000
4.0000
6.0000
8.0000
10.0000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
7.86900e-02 25.9017 2.6384e+00 2.23410e-01 33.3361 6.9047e+001.57212e-01 30.2867 4.9279e+00 3.00870e-01 36.8573 9.3422e+00
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 3 of 5
Thickness method: DeBoerSlope = 7.066
Intercept = 1.400Correlation coefficient, r = 1.000000
Micropore volume = 0.002 cc/g
Micropore area = 5.370 m!/gExternal surface area = 109.300 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 3 of 5
A D BF
0.0
4.0
8.0
12.0
16.0
20.0
24.0
28.0
32.0
36.0
40.0
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+00 5.520e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alexandre Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{1341934593:20090703 134424500} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qpsSample Desc: Pó Comment: Rod 6Sample weight: 0.0877 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.8 min End of run: 2009/07/03 18:07:15 Instrument: Nova Station ACell ID: 6
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/03Analysis performed by:............................................................................................................................................................................................................................................................................................................MBRComments:............................................................................................................................................................................................................................................................................................................Rod 6Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: AInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.0877 gVolume:............................................................................................................................................................................................................................................................................................................0 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.0 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qpsSample Desc: Pó Comment: Rod 6Sample weight: 0.0877 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.8 min End of run: 2009/07/03 18:07:15 Instrument: Nova Station ACell ID: 6
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qpsSample Desc: Pó Comment: Rod 6Sample weight: 0.0877 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.8 min End of run: 2009/07/03 18:07:15 Instrument: Nova Station ACell ID: 6
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 1 of 5
Ads Des
0.00
4.00
8.00
12.00
16.00
20.00
24.00
28.00
32.00
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qpsSample Desc: Pó Comment: Rod 6Sample weight: 0.0877 g Sample Volume: 0 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 81.8 min End of run: 2009/07/03 18:07:15 Instrument: Nova Station ACell ID: 6
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 2 of 5
Slope = 36.309Intercept = 2.346e-01
Correlation coefficient, r = 0.999777C constant= 155.794
Surface Area = 95.299 m!/g
MBET summary
A D BF
0.0000
4.0000
8.0000
12.0000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
8.81160e-02 22.1573 3.4894e+00 2.30529e-01 28.0972 8.5314e+001.58035e-01 25.3428 5.9259e+00 3.00447e-01 30.6600 1.1208e+01
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 3 of 5
Thickness method: DeBoerSlope = 5.696
Intercept = 2.093Correlation coefficient, r = 1.000000
Micropore volume = 0.003 cc/g
Micropore area = 7.191 m!/gExternal surface area = 88.108 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 3 of 5
A D BF
0.0
4.0
8.0
12.0
16.0
20.0
24.0
28.0
32.0
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+00 5.520e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample F_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{345792571:20090703 184511953} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qpsSample Desc: Pó Comment: rod 5Sample weight: 0.1956 g Sample Volume: 0.046856 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 88.0 min End of run: 2009/07/03 18:13:24 Instrument: Nova Station BCell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/03Analysis performed by:............................................................................................................................................................................................................................................................................................................MBRComments:............................................................................................................................................................................................................................................................................................................rod 5Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: BInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.1956 gVolume:............................................................................................................................................................................................................................................................................................................0.046856 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.5 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qpsSample Desc: Pó Comment: rod 5Sample weight: 0.1956 g Sample Volume: 0.046856 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 88.0 min End of run: 2009/07/03 18:13:24 Instrument: Nova Station BCell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qpsSample Desc: Pó Comment: rod 5Sample weight: 0.1956 g Sample Volume: 0.046856 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 88.0 min End of run: 2009/07/03 18:13:24 Instrument: Nova Station BCell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 1 of 5
Ads Des
0.00
4.00
8.00
12.00
16.00
20.00
24.00
28.00
32.00
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qpsSample Desc: Pó Comment: rod 5Sample weight: 0.1956 g Sample Volume: 0.046856 ccOutgas Time: 2.5 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 88.0 min End of run: 2009/07/03 18:13:24 Instrument: Nova Station BCell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 2 of 5
Slope = 36.693Intercept = 2.707e-01
Correlation coefficient, r = 0.999845C constant= 136.545
Surface Area = 94.214 m!/g
MBET summary
A D BF
0.0000
4.0000
8.0000
12.0000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
8.73920e-02 21.7296 3.5260e+00 2.22601e-01 27.3632 8.3727e+001.57620e-01 24.8730 6.0190e+00 3.04077e-01 30.4508 1.1481e+01
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 3 of 5
Thickness method: DeBoerSlope = 5.888
Intercept = 0.785Correlation coefficient, r = 1.000000
Micropore volume = 0.001 cc/g
Micropore area = 3.144 m!/gExternal surface area = 91.070 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 3 of 5
A D BF
0.0
4.0
8.0
12.0
16.0
20.0
24.0
28.0
32.0
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+00 5.550e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/03 Operator: Date:7/3/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample G_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{306759231:20090703 184343687} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.0848 g Sample Volume: 0.019378 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 66.3 min End of run: 2009/07/06 16:12:31 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/06Analysis performed by:............................................................................................................................................................................................................................................................................................................MBRComments:............................................................................................................................................................................................................................................................................................................Rod 5Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: AInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.0848 gVolume:............................................................................................................................................................................................................................................................................................................0.019378 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.0 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.0848 g Sample Volume: 0.019378 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 66.3 min End of run: 2009/07/06 16:12:31 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.0848 g Sample Volume: 0.019378 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 66.3 min End of run: 2009/07/06 16:12:31 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 1 of 5
Ads Des
0.00
2.00
4.00
6.00
8.00
10.00
Vol
ume
@ S
TP (c
c/g)
0.00 0.04 0.08 0.12 0.16 0.20 0.24 0.28 0.32
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qpsSample Desc: Pó Comment: Rod 5Sample weight: 0.0848 g Sample Volume: 0.019378 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 66.3 min End of run: 2009/07/06 16:12:31 Instrument: Nova Station ACell ID: 5
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 2 of 5
Slope = 123.339Intercept = -1.060e+00
Correlation coefficient, r = 0.999016C constant= -115.395
Surface Area = 28.480 m!/g
MBET summary
A D BF
-1.1700
4.0000
8.0000
12.0000
16.0000
20.0000
24.0000
28.0000
32.0000
36.0000
40.0000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
8.02270e-02 7.5258 9.2734e+00 2.27764e-01 8.8847 2.6561e+011.54834e-01 8.3233 1.7611e+01 3.00599e-01 9.4277 3.6476e+01
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 3 of 5
Thickness method: DeBoerSlope = 1.159
Intercept = 3.615Correlation coefficient, r = 1.000000
Micropore volume = 0.006 cc/g
Micropore area = 10.557 m!/gExternal surface area = 17.923 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 3 of 5
A D BF
0.0
2.0
4.0
6.0
8.0
10.0
Vol
ume
@ S
TP (c
c/g)
0.000e+00 8.000e-01 1.600e+00 2.400e+00 3.200e+00 4.000e+00 4.800e+00 5.520e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:MBR Date:2009/07/06 Operator: Date:7/6/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample H_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{241628632:20090706 171356843} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qpsSample Desc: Pó Comment: rod 66Sample weight: 0.0529 g Sample Volume: 0.014079 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 669.4 min End of run: 2009/07/10 4:56:57 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 1 of 5
Administrative inormationAnalysis performed on:............................................................................................................................................................................................................................................................................................................2009/07/10Analysis performed by:............................................................................................................................................................................................................................................................................................................AlexComments:............................................................................................................................................................................................................................................................................................................rod 66Instrument:............................................................................................................................................................................................................................................................................................................NOVA Station: AInstrument version:............................................................................................................................................................................................................................................................................................................0.00Software version:............................................................................................................................................................................................................................................................................................................2.11
Sample informationId:............................................................................................................................................................................................................................................................................................................HAp_ZnDescription:............................................................................................................................................................................................................................................................................................................PóWeight:............................................................................................................................................................................................................................................................................................................0.0529 gVolume:............................................................................................................................................................................................................................................................................................................0.014079 cc
Sample preparation informationOutgas time:............................................................................................................................................................................................................................................................................................................2.0 hrsOutgas temperature:............................................................................................................................................................................................................................................................................................................200.0 C
Analysis informationAmbient temperature:............................................................................................................................................................................................................................................................................................................298 CThermal delay:............................................................................................................................................................................................................................................................................................................60 secPressure tolerance:............................................................................................................................................................................................................................................................................................................0.100/0.100 (ads/des)Equilibration time:............................................................................................................................................................................................................................................................................................................180/180 sec (ads/des)Equilibration timeout:............................................................................................................................................................................................................................................................................................................360/360 sec (ads/des)
Analysis Data
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qpsSample Desc: Pó Comment: rod 66Sample weight: 0.0529 g Sample Volume: 0.014079 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 669.4 min End of run: 2009/07/10 4:56:57 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qpsSample Desc: Pó Comment: rod 66Sample weight: 0.0529 g Sample Volume: 0.014079 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 669.4 min End of run: 2009/07/10 4:56:57 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 1 of 5
Ads Des
0.00
40.00
80.00
120.00
160.00
200.00
240.00
280.00
313.00
Vol
ume
@ S
TP (c
c/g)
0.00 0.20 0.40 0.60 0.80 1.00 1.09
Relative Pressure, P/Po
Isotherm * Linear
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qpsSample Desc: Pó Comment: rod 66Sample weight: 0.0529 g Sample Volume: 0.014079 ccOutgas Time: 2.0 hrs OutgasTemp: 200.0 CAnalysis gas: Nitrogen Bath Temp: 77.3 KPress. Tolerance:0.100/0.100 (ads/des) Equil time: 180/180 sec (ads/des) Equil timeout: 360/360 sec (ads/des)Analysis Time: 669.4 min End of run: 2009/07/10 4:56:57 Instrument: Nova Station ACell ID: 66
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 1 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 2 of 5
Slope = 34.342Intercept = 6.746e-02
Correlation coefficient, r = 0.999663C constant= 510.055
Surface Area = 101.208 m!/g
MBET summary
A D BF
0.0000
4.0000
8.0000
11.6000
1 / [
W((
Po/
P) -
1) ]
0.000e+00 8.000e-02 1.200e-01 1.600e-01 2.000e-01 2.400e-01 2.800e-01 3.200e-01
Relative Pressure, P/Po
Multi-Point BET Plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 2 of 5
Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ] Relative|Pressure Volume @ STP 1 / [ W((Po/P) - 1) ]
[P/Po] [cc/g] [P/Po] [cc/g]
8.02510e-02 24.1435 2.8916e+00 2.23021e-01 30.0838 7.6340e+001.50559e-01 27.3444 5.1863e+00 3.01798e-01 32.9138 1.0508e+01
Multi-Point BET
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 2 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 3 of 5
Thickness method: DeBoerSlope = 5.635
Intercept = 4.621Correlation coefficient, r = 0.999994
Micropore volume = 0.007 cc/g
Micropore area = 14.044 m!/gExternal surface area = 87.165 m!/g
V-t method summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 3 of 5
A D BF
0.0
4.0
8.0
12.0
16.0
20.0
24.0
28.0
32.0
36.0
40.0
Vol
ume
@ S
TP (c
c/g)
0.000e+00 1.200e+00 2.000e+00 2.800e+00 3.600e+00 4.400e+00 5.200e+00 6.000e+00
Statistical Thickness (Å)
V-t plot
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 3 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 4 of 5
Surface Area = 90.075 m!/gPore Volume = 0.431 cc/g
Pore Radius Dv(r) = 65.122 Å
BJH adsorption summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 4 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 4 of 5
V dV(r)
0.00e+00
3.14e-04
6.28e-04
9.42e-04
1.26e-03
1.57e-03
1.88e-03
2.20e-03
2.51e-03
2.83e-03
3.14e-03
3.46e-033.73e-03
dV(r) (cc/Å
/g)
0.00e+00
4.00e-02
8.00e-02
1.20e-01
1.60e-01
2.00e-01
2.40e-01
2.80e-01
3.20e-01
3.60e-01
4.00e-01
4.40e-014.75e-01
Cum
ulat
ive
Por
e V
olum
e (c
c/g)
10.000 20.000 30.000 40.000 100.000 200.000 300.000 500.000
Pore Radius (Å)
BJH method Adsorption dV()
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 4 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 5 of 5
Surface Area = 114.942 m!/gPore Volume = 0.443 cc/g
Pore Radius Dv(r) = 93.742 Å
BJH desorption summary
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 5 of 5
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 5 of 5
V dV(r)
0.00e+00
6.93e-04
1.39e-03
2.08e-03
2.77e-03
3.46e-03
4.16e-03
4.85e-03
5.54e-03
6.23e-03
6.93e-03
7.62e-03
8.31e-03
dV(r) (cc/Å
/g)
0.00e+00
4.00e-02
8.00e-02
1.20e-01
1.60e-01
2.00e-01
2.40e-01
2.80e-01
3.20e-01
3.60e-01
4.00e-01
4.40e-01
4.80e-01
Cum
ulat
ive
Por
e V
olum
e (c
c/g)
10.000 20.000 30.000 40.000 100.000 200.000 300.000 500.000
Pore Radius (Å)
BJH method Desorption dV()
Quantachrome NovaWin2 - Data Acquisition and Reductionfor NOVA instruments
©1994-2007, Quantachrome Instrumentsversion 9.0
Analysis ReportOperator:Alex Date:2009/07/10 Operator: Date:7/10/2009Sample ID: HAp_Zn Filename: C:\QCdata\Physisorb\Sample E_long run_FEUP.qps
Quantachrome NovaWin2 - Data Acquisition and Reduction for NOVA instruments ©1994-2007, Quantachrome Instruments version 9.0 Report id:{894749148:20090710 102953656} Page 5 of 5