Tbur (Newton)Pascal (1921) DECHEMA Vol I Parte 1a (Sup 1) pag 82-85Peng-RobinsonNombreTc [K]Pc [bar]wKijEthylene-OxideWaterAJUSTE DE PRSV-HYSYS (Regla de mezclado de margules) A DATOS EXPERIMENTALESCALCULADOSERRRORESCon EqfasesERRRORESEthylene-Oxide469.1571.90.197447Ethylene-Oxide-0.1643059704P (mmHg)T (C)X EOY EOP (bar)T (C)Y EOFuncin ObjetivoT (C)Y EOT (K)T (C)Y EOT (K)Y EOWater647.13220.550.344861Water-0.16430597041. INTRODUCIR LA INFORMACIN DE LOS COMPONENTES PUROS (Tc, Pc, Omega, Kappa 1)176099.000.00020.01061.0132599.610.0064937.873E-140.61-0.004107374.303101.1530.0077522.15334-0.002848276098.100.00040.02521.0132599.430.0129439.644E-141.33-0.012257374.093100.9430.0154462.84309-0.009754P (bar)1.013251.013251.013251.01724967111.01724967111.01724967111.01724967111.01724967111.01724967111.01724967111.01724967111.01724967111.01724967111.01724967111.01724967111.017251.017251.017251.01724967112. INTRODUCIR ESTIMACIN INICIAL DE LOS PARMETROS DE INTERACCIN (k12, k21)376097.000.00070.05081.0132599.160.0225405.183E-132.16-0.028260373.778100.6280.0268803.62811-0.023920X OxEtil0.00020.00040.00070.15000.25000.35000.40000.47000.50000.54300.57200.60000.62500.63200.66700.70000.73600.75000.8070476352.500.15001.0172536.360.9455481.011E-09-16.14311.94238.7920.945476-13.70750X H2O0.99980.99960.99930.85000.75000.65000.60000.53000.50000.45700.42800.40000.37500.36800.33300.30000.26400.25000.19303. INTRODUCIR LA INFORMACIN EXPERIMENTAL576340.500.25001.0172528.160.9675153.541E-10-12.34305.24632.0960.964383-8.40359T Bur (K)374.30334Tb [K]374.09309Tb [K]373.77811Tb [K]311.94250Tb [K]305.24641Tb [K]301.33098Tb [K]299.68453Tb [K]297.52824Tb [K]296.63775Tb [K]295.38635Tb [K]294.55624Tb [K]293.76395Tb [K]293.06352Tb [K]292.86852Tb [K]291.90043Tb [K]290.99770Tb [K]290.02327Tb [K]289.64689Tb [K]288.13050Tb [K]676334.500.35001.0172525.590.9729441.199E-10-8.91301.33128.1810.973142-6.319020.0077521044=Y(1)0.0154462564=Y(1)0.0268795916=Y(1)0.9454758805=Y(1)0.9643827012=Y(1)0.9731423151=Y(1)0.9764077703=Y(1)0.9803855105=Y(1)0.9819364375=Y(1)0.9840302227=Y(1)0.9853657359=Y(1)0.9866019096=Y(1)0.9876642118=Y(1)0.9879549559=Y(1)0.9893666637=Y(1)0.990636591=Y(1)0.9919585606=Y(1)0.992405518=Y(1)0.9944154508=Y(1)4. UTILIZAR SOLVER PARA AJUSTAR LOS PARMETROS DE INTERACCIN BINARIOS776332.000.40001.0172525.150.9738647.086E-11-6.85299.68526.5350.976408-5.465470.9922478956=Y(2)0.9845537436=Y(2)0.9731204084=Y(2)0.0545241195=Y(2)0.0356172988=Y(2)0.0268576849=Y(2)0.0235922297=Y(2)0.0196144895=Y(2)0.0180635625=Y(2)0.0159697773=Y(2)0.0146342641=Y(2)0.0133980904=Y(2)0.0123357882=Y(2)0.0120450441=Y(2)0.0106333363=Y(2)0.009363409=Y(2)0.0080414394=Y(2)0.007594482=Y(2)0.0055845492=Y(2)876329.900.47001.0172524.940.9743343.236E-11-4.96297.52824.3780.980386-5.521763Iteraciones3Iteraciones3Iteraciones4Iteraciones4Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones3Iteraciones2Iteraciones2Iteraciones5. OBTENER DE EQFASES LA INFORMACIN DE LOS COMPONENTES PUROS (Tc, Pc, Omega)976329.000.50001.0172524.910.9743922.186E-11-4.09296.63823.4880.981936-5.51225Coef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.VCoef.Fug.LCoef.Fug.V1076327.000.54301.0172524.900.9744351.327E-11-2.10295.38622.2360.984030-4.7636538.23672682750.986587543538.09589010460.986616227137.88538035430.98665809266.1973811620.98321681013.78903414960.98224342182.7292635010.98163759942.3955058740.9813744662.04632118440.98102213881.92629954590.98087403781.7771617440.98066329911.68910888490.98052180021.61208113270.98038546391.54907291640.98026388021.53231341030.98022985271.45373017150.98005977071.38674859470.97989942331.32044287840.97972442411.2963441970.97965628591.20679773440.9793787156. OBTENER DE EQFASES LOS VALORES INICIALES DE LOS PARMETROS DE INTERACCIN BINARIOS (k12=k21)1176327.200.57201.0172524.880.9744801.158E-11-2.32294.55621.4060.985366-5.793760.98395639470.99144451450.97650907250.99143113740.96543867040.99141034250.06296515790.9815799260.04655627250.98034321460.04052405920.97959692910.03853808020.97927710160.03624305770.97885195990.03536940890.9786742080.03419871420.97842218080.03345426340.97825352530.03276531250.97809143450.03217276470.97794721160.03201046160.97790690210.03122146440.97770576480.03051038090.97751664860.02976918220.97731079120.02948997840.97723140760.0284080840.97690533151276326.800.60001.0172524.850.9745689.158E-12-1.95293.76420.6140.986602-6.18605Lquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OKLquido OKVapor OK7. UTILIZAR SOLVER PARA AJUSTAR EL PARMETRO DE INTERACCIN BINARIO1376326.500.62501.0172524.810.9747048.264E-12-1.69293.06419.9140.987664-6.58648Zeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.VapZeta.LiqZeta.Vap1476326.400.63201.0172524.790.9747557.668E-12-1.61292.86919.7190.987955-6.681480.0007338310.99133794250.00073430010.99128697360.00073500430.99121152310.00100858260.98286699330.00114176040.98188361410.00127288380.98126999320.00133936370.98100295770.00143407170.98064495340.00147533110.98049430920.00153523790.98027978880.00157617980.98013564190.00161614350.97999667080.00165219980.9798726680.00166236060.97983795170.00171360640.97966434920.00176262290.97950056430.00181691070.97932168210.00183826330.9792518710.00192666350.97896797131576325.900.66701.0172524.680.9751085.820E-12-1.22291.90018.7500.989367-7.149571676325.400.70001.0172524.530.9756313.986E-12-0.87290.99817.8480.990637-7.552301776325.000.73601.0172524.300.9764713.593E-12-0.70290.02316.8730.991959-8.126731876324.900.75001.0172524.190.9768883.907E-12-0.71289.64716.4970.992406-8.403111976324.500.80701.0172523.650.9792332.543E-12-0.85288.13014.9800.994415-9.51950CALCULO DE LA TEMPERATURA DE BURBUJA CON LA ECUACIN DE ESTADO: PRSV con Regla de Mezclado de MargulesSuma de cuadrados610.3213760.00096572933.0569080.00067543*Datos de los Componentes PurosParmetros Binarios kijInformacinStryjek, R.; Vera, J.H. (1986) "PRSV: an impoved Peng-Robinson eqution of state for pure compounds and mixtures" Can. J. Chem.Eng., 64, 323-333Regla para PRSV-HYSYS: Margules (1 - xi kij - xj kji)NombreTc (K)Pc (bar)Factor Acntricok11 = Acetaldehido2 = Agua3 = n-HeptanoDatos de la corriente1 = Acetaldehido461.00055.7000.30300-0.081859-0.1056396424Estimacin2 = Agua647.299221.2000.34400-0.076699-0.2434834012Resultados3 = n-Heptano540.15827.3680.349790.072223DATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOSDATOS DE LA CORRIENTEESTIMACIONES INICIALESRESULTADOS*Nombrek0Ci para ai cuando T>Tc,iP (bar)1.013T (K)320.00372.7699.61P (bar)1.013T (K)320.00372.5899.43P (bar)1.013T (K)320.00372.3199.16P (bar)1.017T (K)320.00309.5136.36P (bar)1.017T (K)320.00301.3128.16P (bar)1.017T (K)320.00298.7425.59P (bar)1.017T (K)320.00298.3025.15P (bar)1.017T (K)320.00298.0924.94P (bar)1.017T (K)320.00298.0624.91P (bar)1.017T (K)320.00298.0524.90P (bar)1.017T (K)320.00298.0324.88P (bar)1.017T (K)320.00298.0024.85P (bar)1.017T (K)320.00297.9624.81P (bar)1.017T (K)320.00297.9424.79P (bar)1.017T (K)320.00297.8324.68P (bar)1.017T (K)320.00297.6824.53P (bar)1.017T (K)320.00297.4524.30P (bar)1.017T (K)320.00297.3424.19P (bar)1.017T (K)320.00296.8023.651 = Acetaldehido0.8150949341.432105167x10.0002y10.95000.00649332.463482x10.0004y10.95000.01294332.357906x10.0007y10.95000.02254032.200183x10.1500y10.95000.9455486.303652x10.2500y10.95000.9675153.870059x10.3500y10.95000.9729442.779840x10.4000y10.95000.9738642.434659x10.4700y10.95000.9743342.073051x10.5000y10.95000.9743921.948784x10.5430y10.95000.9744351.794539x10.5720y10.95000.9744801.703637x10.6000y10.95000.9745681.624280x10.6250y10.95000.9747041.559527x10.6320y10.95000.9747551.542333x10.6670y10.95000.9751081.461931x10.7000y10.95000.9756311.393758x10.7360y10.95000.9764711.326727x10.7500y10.95000.9768881.302518x10.8070y10.95000.9792331.2134242 = Agua0.87188204341.4589507217x20.9998y20.05000.9935070.993706x20.9996y20.05000.9870570.987452x20.9993y20.05000.9774600.978145x20.8500y20.05000.0544520.064061x20.7500y20.05000.0324850.043314x20.6500y20.05000.0270560.041624x20.6000y20.05000.0261360.043560x20.5300y20.05000.0256660.048427x20.5000y20.05000.0256080.051216x20.4570y20.05000.0255650.055941x20.4280y20.05000.0255200.059625x20.4000y20.05000.0254320.063579x20.3750y20.05000.0252960.067455x20.3680y20.05000.0252450.068601x20.3330y20.05000.0248920.074751x20.3000y20.05000.0243690.081230x20.2640y20.05000.0235290.089125x20.2500y20.05000.0231120.092447x20.1930y20.05000.0207670.1076023 = n-Heptano0.87986038651.4182632933x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.000000x30.0000y30.00000.0000000.0000001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.00001.0000*Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6Iteracin 1Iteracin 2Iteracin 3Iteracin 4Iteracin 5Iteracin 6P (bar)1.0131.0131.0131.0131.0131.0131.0131.0131.0131.0131.013